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浮法玻璃复合法在线镀双层膜的研究
作者:赵洪力 刘起英 韩冰 张福成 
单位:燕山大学材料科学与工程学院 秦皇岛开发区蓝光玻璃新技术有限公司 燕山大学材料科学与工程学院  燕山大学材料科学与工程学院 河北省亚稳材料制备技术与科学重点实验室  浙江大学蓝星新材料技术有限公司 秦皇岛066004  河北省亚稳材料制备技术与科学重点实验室 
关键词:浮法玻璃  在线镀膜  双层膜  化学气相沉积  电浮法  阳光控制镀膜玻璃 
分类号:TQ171.1
出版年,卷(期):页码:2005,33(11):0-0
DOI:
摘要:
在浮法玻璃生产线的锡槽内和玻璃板面温度600℃的退火窑区分别采用电化学方法和化学气相沉积法,在浮法玻璃表面在线镀膜,制备了双层膜。对双层膜的光谱性能、耐磨性和耐酸碱性进行了测试。用扫描电镜、原子力显微镜对膜的表面形貌和断面进行了观察。结果表明:这种在线复合法制备的双层膜增强了单层膜的阳光控制功能,同时可赋予玻璃多种需要的颜色。双层膜光谱性能和颜色特征可以通过改变工艺条件得到调节。膜层表面均匀,耐磨性、耐酸碱性良好。
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Chemical vapor deposition and electrochemistry were respectively used for on-line depositing a bi-layer film on float glass in a float bath and a lehr gap where the glass surface is 600 ℃.The spectrum properties,anti-wear and chemical stability of the bi-layer film were measured,and in addition the surface morphology and a cross-section of the bi-layer film were analyzed by scanning electron microscopy and atomic force microscopy.The results show that the bi-layer film prepared by the compound technique on-line improves the solar control function of single films and endows the glass with many needed colors.The spectrum properties and colors can be adjusted by changing the technical conditions.The uniform surface of the film has excellent stability against abrasion and erosion of acid and alkali.
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基金项目:
河北省自然科学基金(E2004000241)资助项目
作者简介:
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参考文献:
[1]汪建勋.浮法在线玻璃镀膜工艺技术的概况及发展[J].中国建材装备,1996(6):34—36.WANG Jianxun.Chin Build Mater Equipment(in Chinese),1996(6):34—36. [2]GORDON R.Chemical vapor deposition of coatings on glass[J].J Non-Cryst Solids,1997,218:81—91. [3]MCCURDY J R.Successful implementation methods of at-mospheric CVD on a glass manufacturing line[J].J Thin SolidFilms,1999,351:66—72. [4]ARNAUD A.Industrial production of coated glass:futuretrends for expanding needs[J].J Non-Cryst Solids,1997,218:12—18. [5]陆章明,林云飞,刁铁夫.电浮法玻璃着色机理及钢化退色问题的研究[J].玻璃,1991(5):1—7.LU Zhangming,LIN Yunfei,DIAO Tiefu.Glass(in Chi-nese),1991(5):1—7. [6]全国建筑用玻璃标准化技术委员会.GB/T18915.1—2002镀膜玻璃[S].北京:中国标准出版社,2003.The National Standardize Technology Committee of BuildingGlass.GB/T18915.1—2002 Coating Glass(in Chinese).Bei-jing:Standards Press of China,2003. [7]陆章明,林云飞.电浮法玻璃着色层与微观结构的研究[J].中国玻璃,1991(4):1—6.LU Zhangming,LIN Yunfei.Chin Glass(in Chinese),1991(4):1—6.
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