硅酸盐学报

复合活化剂对高掺量矿渣胶凝材料性能及其作用机理的影响

作者：姜骞1 2 穆松1 2 刘建忠1 2 石亮1 2

单位：1. 江苏苏博特新材料股份有限公司南京 211103 2. 高性能土木工程材料国家重点实验室南京 210008

关键词：高掺量矿渣胶凝材料复合活化剂水化机理

分类号：TU528.042.1

出版年,卷(期):页码：2016,44(8):1147-1153

DOI：10.14062/j.issn.0454-5648.2016.08.10

摘要：

针对水泥-高掺量矿渣胶凝材料早期强度发展缓慢的现象，自行设计开发了一种用于激发矿渣早期水化活性的复合活化剂，对比研究了复合活化剂与纯硫酸盐对水泥-矿渣胶凝材料性能以及水化机理的影响。结果表明：复合活化剂与纯硫酸盐均能在水化1 d内提高水泥熟料和矿渣的反应程度，促进矿渣产物形态提前由外部水化产物向内部水化产物过渡，提升胶凝材料早期宏观性能；然而使用纯硫酸盐激发的胶凝材料后期性能下降，可能是由于生成过量钙矾石所造成；复合活化剂则通过促进水泥熟料水化、加速矿渣溶解、反应以及改善微观结构性能等提高胶凝材料早期强度提升，对后期性能无副作用。

A composite activator was developed to activate a high volume slag-cement binder material for a high early-age strength. The influence of amount of the composite admixture on the properties and hydration mechanism of high volume slag-cement binder material was investigated. The results show that the composite admixture can increase the reaction extent of both cement clinker and slag simultaneously, and enhance the time of transition from outer hydration products to inner hydration products. The macroscopic properties of slag-cement binder material can be promoted by both composite admixture and pure sodium sulfate in early age. However, the performance degradation occurs when the amount of sodium sulfate increases due to too much ettringite formed. The composite admixture accelerates cement hydration rate, dissolution and reaction of slag, and improves the microstructural properties of binder to achieve a higher early-age strength without any side-effect on the late performance.

基金项目：

国家“973”计划(SQ2015CB060428)；国家自然科学基金(51308262)资助项目。

作者简介：

姜骞(1988—)，男，硕士，助理工程师。

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