硅酸盐学报

Al2O3/SiO2摩尔比对无碱铝硼硅酸盐玻璃黏温特性的影响

作者：李青1 2 张广涛1 2 李赫然3 郑权1 2 王丽红1 2

单位：1. 东旭集团有限公司石家庄 050021 2. 平板显示玻璃技术和装备国家工程实验室石家庄 050035 3. 北京大学光华管理学院北京 100871

分类号：TQ171.112

出版年,卷(期):页码：2017,45(10):0-0

DOI：

摘要：

用高温熔融法制备了Al2O3/SiO2比变化的无碱铝硼硅酸盐玻璃。固定无碱铝硼硅酸盐玻璃体系中SiO2与Al2O3总量不变，研究了用Al2O3替代SiO2对玻璃的熔化温度、成型温度、退火点、应变点等特征黏度参考点的影响；通过红外光谱和Raman光谱研究其结构变化。结果表明：随着铝硅比n(Al2O3/SiO2)逐渐增加，玻璃网络中非桥氧减少，导致退火点(Ta)和应变点(Tst)不断升高；同时，在高温下，熔化温度(Tm)和成型温度(Tf)呈现下降趋势。

基金项目：

作者简介：

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