硅酸盐学报

全无机铅卤钙钛矿CsPbX3晶体研究进展

作者：王娜1 申慧1 3 金敏2 徐家跃1 李海霞1 田甜1 张彦1

单位：(1. 上海应用技术大学材料科学与工程学院上海 201418 2. 上海电机学院材料科学与工程学院上海 201306 3. 山东大学晶体材料国家重点实验室济南 250100)

关键词：全无机铅卤钙钛矿光电性能晶体生长

分类号：O782

出版年,卷(期):页码：2019,47(7):0-0

DOI：

摘要：

铅卤钙钛矿APbX3(A=阳离子(如CH3NH3或Cs) X=Cl、Br、I)由于其卓越的光电特性，在太阳能电池、LED、光电探测等领域备受关注，成为全世界关注的焦点。CsPbX3 (X=Cl、Br、I)晶体同时也是性能优异的室温X/γ射线探测材料，其能量分辨率优于目前商用的碲锌镉(CZT)晶体，极具研究价值。本综述主要围绕全无机铅卤钙钛矿的晶体结构、主要光电特性和潜在应用，重点对CsPbX3晶体的生长方法进行归纳和比较，包括逆温结晶、抗溶剂蒸汽辅助结晶、Bridgman法、区熔法等，将有助于人们对全无机铅卤钙钛矿CsPbX3晶体生长特性的认识，并为未来该体系晶体制备和性能研究提供参考。

In recent years, lead-halide perovskite APbX3 (A=cations (such as CH3NH3 or Cs), X=Cl, Br, I) has attracted much attention in the fields of solar cells, LEDs, and photodetection due to its excellent optoelectric properties. CsPbX3 (X=Cl, Br, I) crystals are also excellent room-temperature X/γ ray detection materials, in which its energy resolution is better than that of the existing commercial CdZnTe (CZT) crystal. This review mainly deals with recent studies on the structure, optoelectronic properties and potential applications of all-inorganic lead-halide perovskite. The main growth methods of CsPbX3 crystals, i.e., inversion temperature crystallization method, antisolvent vapor-assisted crystallization, the Bridgman method, zone melting method and so on, were summarized and analyzed. This review could clarify the growth characteristics of all inorganic lead-halide perovskite CsPbX3 crystals, and provide a valuable reference for the research of CsPbX3 crystal in the future.

基金项目：

国家自然科学基金(51572175，61605116)；上海市自然科学基金(15ZR1440600)资助项目。

作者简介：

参考文献：

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